Homogeneous Catalyzed Ozone Decomposition in the Presence of Co(II).

The homogeneous decomposition of ozone in the presence of a Co(II) catalyst has been investigated in aqueous solution. Under the conditions investigated (Co(II) concentration: 0.0 – 2.0?ppm, pH: 1.6- 8.4, O₃ concentration: 5 10^?5 – 2.0 10⁴?M) the process can be assumed to follow pseudo first order kinetics with respect to ozone. Cobalt concentration dependency also obeys first order kinetics although it may be considered to reach a steady state concentration. pH exerts a positive influence on the decomposition rate from 1.6 to 7.1, the process leveling off at pH 8.4. An Arrhenius analysis of the temperature effect gave a moderate activation energy of the global reaction (E=10917?cal mol^?1). A more detailed radical mechanism than a simple pseudo first order reaction can be postulated for simulation purposes. By numerical optimization of some unknown kinetic constants the influence of several operating variables can be adequately predicted.     

环氧丙烷嵌入乙酸酐合成1,2-丙二醇二乙酸酯的绿色化学途径

用Mg-Al基复合物催化环氧丙烷(PO)一步嵌入乙酸酐(AA)合成了1,2-丙二醇二乙酸酯(PGDA),经红外光谱、电喷雾质谱鉴定得到了预期产物。研究了反应温度、n(PO)/n(AA)、PO滴加或一次性投入方式对单PO加成选择性的影响。实验结果表明,当Mg-Al基复合物用量为1.6 g/100 g AA,n(PO)/n(AA)=1,以0.75g/min滴加PO,反应温度130~135℃时,单PO加成选择性达到w(PGDA)=98.2%。与传统合成二元醇二酯的方法相比,该路线无需过量加入AA原料,亦不生成副产物,是一条具有工业化前景的合成二元醇二酯的高原子经济性的绿色化学途径。     

Aqueous electrochemical intercalation of bromine into graphite fibers

For the first time, graphite fibers have been electrochemically intercalated with Br⁻ that have the same structure and properties as those intercalated from vapor phase Br₂. This was accomplished by intercalating pitch-based Thornel^® K-1100 graphite fibers at low temperature (near 0 °C) and high currents (2 A) for long times (6 h). The mechanism appears to be that Br⁻ is oxidized to aqueous Br₂ which, when sufficient local concentration builds up, intercalates the fiber. This was confirmed by intercalating K-1100 fiber in a saturated aqueous Br₂ solution without passing an electrical current. The applied voltage does apparently lower the activation energy of the reaction as evidenced by the observation that P-120 and P-100 fibers will not intercalate in aqueous Br₂ unless a voltage is applied.     

基于卷积树核的中文微博情感要素识别

情感要素识别是情感分析的关键子任务之一,其目的是识别出文本情感所作用的情感对象。文本情感要素识别属于最细粒度的情感分析,吸引了大量研究者的关注。中文微博由于其语言简短灵活、文本不规范、噪声较大等特点,给中文微博情感分析研究工作带来了新的挑战。目前大部分情感要素识别方法都是基于规则的方法或者基于扁平化特征的统计学习方法,区分噪声的能力不强,性能提升有限。针对中文微博的特点,提出一种基于卷积树核的情感要素识别算法,即首先对句子进行词性标注与依存关系分析,将句子中的名词作为候选情感要素;然后基于两种不同的修剪策略对依存树进行修剪,以获取每个候选情感要素的结构化信息;最后采用卷积树核计算依存树的相似度,并在此基础上识别句子中的情感要素。NLPCC2012和NLPCC2013中文微博情感分析评测任务中的实验验证了该方法的性能,其准确率相比于传统方法有显著提升。     

一种改进的基于分解的多目标进化算法

利用基于分解的多目标进化算法框架(MOEA/D),将混合策略的进化算法用于求解分解后的若干单目标优化子问题,提出了一种带局部搜索的基于分解的多目标混合策略进化算法(LMS-MOEA/D)。算法利用均匀设计产生子问题的聚合权重向量,混合交叉策略能够充分利用不同交叉算子的优势;同时算法针对演化过程收敛的特点,结合局部搜索策略,获得逼近Pareto前沿的最优解集。最后通过实验验证算法在多样性和收敛性方面的有效性。     

在线视频点播系统节能方法与策略研究

目前随着海量数据应用的快速发展,如何减少海量数据存储造成的巨大能耗成为研究热点。分析了在线视频点播的海量存储系统,根据正态分布分析视频访问的时间段,结合磁盘的特点提出一种基于视频点播的节能策略。策略中将磁盘的状态划分为不同的等级,降级时根据历史时间间隔调整时间窗口,同时根据视频的种类制定分布,以最终满足系统的性能和节能需求。根据计算,使用节能策略后系统平均节能达到44%。     

一种改进的小波域图像修复算法

针对全变分小波图像修复算法在平滑区易产生阶梯效应并且噪声抑制不充分的缺陷,提出一种新颖的小波域图像修复模型。通过优化一个全变分和图像梯度的二范数的能量泛函来实现小波域的图像修复,使得在去除噪声的同时较好地保留了图像的边缘,在平滑区域削弱了阶梯效应,并利用有限差分法对所建立的扩散方程进行数值求解。实验结果表明:所提方法对于不同丢失比例的图像以及噪声图像都取得了较好的修复效果,尤其当小波系数丢失率较高时更为明显。     

Exploration of mesoporous structure of tunisian raw and acid-leached phosphate ore particles

Rock phosphate fractions were examined for their porous structure by nitrogen adsorption. The pore size distribution and the shape of pores does not seem to depend on the particle size. The specific surface area values present two regions, one above and one below that of the particles with 125 μrn diameter. Particles of a given size were leached with dilute phosphoric acid (1.5 mass% P₂O₅) at 25°C. It was observed that there is a widening of the initial pores during leaching. The particles collected at the initial period of the reaction are pitted and those collected at the final period are disintegrated.     

一种MMC型VSC-HVDC系统预充电的控制策略

模块化多电平换流器(Modular Multilevel Converter,MMC)是一种新型的电压源换流器拓扑,很适合于柔性直流输电(Voltage Source Converter Topology Applied in Voltage Source Converter-high Voltage Direct Current,VSC-HVDC)场合。在系统正常运行之前,MMC中的电容需进行预充电操作,以建立额定的电容电压和直流母线电压。首先介绍了传统启动方式存在的缺陷,为弥补这些不足,结合MMC启动时的数学模型,在详细分析换流器电容预充电动态过程的基础上,采用载波移相(Carrier Phase Shifted Modulation,CPSM)策略提出了一种适用于MMC可控阶段的新型启动方法。设计了电容电压参考值给定方式、内环电流控制以及外环电压控制,该预充电策略在限制过电流和避免过电压的同时,兼顾启动的速度和效率,提高了柔性直流输电系统启动的快速性和可靠性。由在Matlab/Simulink中所构建模型的仿真结果可以看出,所提出的控制策略正确、有效。     

Oxidation behavior and protection of carbon/carbon composites prepared using rapid directional diffused CVI techniques

The oxidation kinetics of carbon/carbon (C/C) composites prepared using a rapid directional diffused (RDD) CVI process were studied. The results showed that the Arrhenius curve for the RDD CVI C/C composites consists of two straight lines, the intercept of which is at about 700 °C at the linear oxidation stage. The oxidation rates are controlled by the surface reaction at 600-700 °C, and the corresponding activation energy is 121 kJ/mol. Between 700 and 800 °C, the oxidation rates are dominated by chemical reaction and diffusion, and the relevant activation energy is 80 kJ/mol. SEM investigation showed that the oxidation starts with original pores on the C/C composite surface with the carbon fiber and matrix oxidized simultaneously. An inexpensive and easily pasted coating containing epoxy organic silicon resin, borates, refractory particulates, etc. was developed. After isothermal temperature, thermal cycle and immersion water oxidation tests, the coating was demonstrated to exhibit good oxidation-resistance properties. The oxidation-resistant mechanism of the coating is discussed.